CHEMISTRY: ELECTROLYTES
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Electrolytes in the human body
- Electrolytes are required in the body to maintain balance between intracellular and extracellular liquids. In particular, it is important to maintain the osmotic gradient between inside and outside.
- Electrolyte balance is maintained by oral and intravenous intake
- Kidneys flush out excess electrolytes
- Dehydration and overhydration are caused by electrolyte imbalance
- Hormones that maintain electrolyte balance are antidiuretic hormone, aldosterone and parathyroid hormone
- The most common electrolyte in the body is salt (sodium chloride)
Functions of electrolytes in the body
- Maintain blood pH
- Muscle and neuron activation
- Hydration of the body
Other common applications of electrolytes
- Sports drinks
- Batteries
- Fuel cells
- Electroplating
- Capacitors
Sports Drinks
- Sports drinks replenish the body’s water and electrolyte levels after dehydration caused by exercise, vomiting, diarrhea etc.
- They are made of electrolytes containing sodium and potassium salts
- Examples of sports drinks: Glucon-D, Gatorade etc
- Simplest electrolyte drink that can be made at home is water + sugar + salt
Batteries
Battery |
Electrode
|
Electrolyte
|
Other notes
|
Alkaline |
Zinc, Manganese oxide
|
Potassium Hydroxide
| |
Daniell cell |
Copper, Zinc
|
Copper sulphate, zinc sulphate
| |
Leclanche cell |
Zinc, carbon
|
Ammonium chloride
|
Precursor of modern dry cell
|
Voltaic pile |
Copper, zinc
|
Brine
|
First electric battery, invented in 1880
|
Zinc carbon |
Zinc, carbon, manganese dioxide
|
Zinc chloride, ammonium chloride
|
Most common battery
|
Zinc chloride |
Same as above
|
Zinc chloride
|
Improvement on zinc carbon battery
|
Lead-acid |
Lead, lead dioxide
|
Sulphuric acid
|
Oldest rechargeable battery
Used in vehicles as they provide high surge currents
|
Lithium-ion |
Graphite, Lithium Cobalt oxide
|
Non-aqueous lithium salts
|
Rechargable
Slow self-discharge, high energy to weight ratio
|
Nickel Cadmium |
Nickel oxide hydroxide, cadmium
|
Rechargable
Last longer, more stable than lithium ion
| |
Fuel cell |
Hydrogen (fuel), oxygen (oxidant)
|
Polymer membrane
Aqueous alkaline solution
|
Consumes reactant from an external source
High energy efficiency and high reliability
No moving parts
Used in space shuttles, submarines
|
Common electrolytes and their uses
Electrolyte |
Uses
|
Other notes
|
Sodium chloride |
Primary component of extracellular fluid
Food preservative
| |
Sodium hydroxide
(caustic soda)
|
Manufacture of paper, soaps, detergents, drain cleaners
Purification of drinking water
| |
Silver nitrate |
Photographic films
Water disinfection (esp. on space shuttles)
| |
Hydrochloric acid |
Manufacture of PVC, household cleaners
Food additives (like gelatin)
Leather processing
|
Found naturally in gastric acid
|
Sulphuric acid |
Lead-acid batteries
Ore processing
Fertilizer manufacture
|
Soluble in water at all concentrations
One of the largest products of chemical industry
|
Nitric acid |
Determining metal traces in solutions
Wood finishing
|
Colourless when pure, yellows with age
Highly corrosive
|
Acetic acid |
Manufacture of soft drink bottles
Photographic films
Synthetic fibres and fabrics
|
Dilute acetic acid is called vinegar
|
Ammonium hydroxide
(aqueous ammonia)
|
Cleaning agent
| |
Calcium hydroxide
(slaked lime or pickling lime)
|
Sewage treatment
Whitewash, plaster, mortar
Hair relaxers
|
Natural mineral form is called portlandite
(rare mineral occurring in volcanic rocks)
|
THANKS
JOHAR
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